Organic сhemistry

Chemical properties of organic compounds derived from ammonia. The mechanism of substitution of hydrogen for hydrocarbon radicals within molecules. Classification of the most common amines. Familiarization with the formula for the secondary amine.

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  • Mechanistic aspects of the Diels-Alder reaction. The effect of micelles on it. The effects of Lewis acids on the endo-exo selectivity in water compared to the effects in organic solvents. Enantioselective cid catalysis of an organic reaction in water.

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  • General properties of organometallic complexes. Metal alkyls and hydrides. Nucleophilic and electrophilic addition. Physical methods in organometallic chemistry. Insertion and Elimination. Homogeneous catalysis. Applications to organic synthesis.

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  • Physico-chemical characteristics of I-40 and MS-20 commercial mineral oils. The use of such oils for the lubrication of molds in the manufacture of glass containers. The study of the thermal stability of oils and their fractions of hydrocarbons.

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  • Rubidium as a chemical element and a soft, silvery-white metallic element of the alkali metal group. Characteristics, history, occurrence rubidium. Isotopes, uses and applications. Compounds, rubidium chloride. Precautions and biological effects.

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  • Electrochemical lithiation reactions of electrodes made of R5M3 alloys were studied in an organic electrolyte containing LiPF6 salt, using the conventional charge-discharge technique, and the reaction products were analyzed by X-ray powder diffraction.

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  • The mechanism of binding of Cr(acac)3 molecules at active sites of the surface of silica and alumina supports. Silica support due to hydrogen bonding with acetylacetonate ligand. Interaction of p-electrons of acetylacetonate ligands with Al3+ sites.

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  • Magnesium as a chemical element and a silvery-white, light-weight metal. Notable characteristics, applications. As the metal. Incendiary use, in magnesium compounds. History, sources, ores, sea water, electrolysis. Biological role, isotopes, precautions.

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