Synthesis of Perfluoroalkyl Heterocycles Using Perfluoroolefins Containing a Reactive Group at the Double Bond
Reactions of Thiocyanate and Isothiocyanate Derivatives of Fluoroolefins with N-Nucleophilic Reagents. The Influence of the N-Nucleophile on the Construction of Six-Membered Heterocycles. The Use of Fluoroolefins with a Carbonyl-Containing Substitutent.
Подобные документы
The method of synthesis of fluorinated heterocycles. The use of mono- and 1,3-dicarbonyl substrates and their nitrogen-containing analogues. Biological activity, physical and chemical properties of heterocyclic compounds with perfluoroalkyl groups.
научная работа, добавлен 05.03.2013Substituent tautomerism of six-membered ring heterocycles. Compounds with one, two or more potentially tautomeric functional group. The prototropic tautomerism of hydroxypyridine is a prototype for oxo-hydroxy tautomerization processes in heterocycles.
статья, добавлен 05.03.2013Reductive opening of heterocycles as a source of functionalized organolithium compounds. Methods for homologation of heterocycles. Double lithiation of thianthrene. Phthalan: a versatile starting material. Homologation of six-membered heterocycles.
статья, добавлен 05.03.2013Heterocycles with one, two, three and four heteroatoms. Fused heterocycles incorporating pyridine rings. Quinolines, isoquinolines, and their fused rings. Spiroheterocycles and a solvent-free one-pot reaction of a mixture of meldrum’s or barbituric acid.
учебное пособие, добавлен 05.03.2013Purines Fused to Six-Membered Heterocycles. Pyrido-, pyridazino-, pyrimido-, pyrazino-, oxazino-, thiazino-, triazino-purines. Purines Fused to Seven- and Eight-Membered Heterocycles. Oxdiazocino- and Thiadiazocino-Purines Efforts to obtain compounds.
статья, добавлен 05.03.2013Purines fused with five-membered heterocycles: pyrrolo-, oxazolo-, thiazolo-, imidazo-, pyrazolo-, triazolo- and tetrazolo-purines. Purines annulated with five-membered rings. Compounds with a greater selective efficacy without the unwanted side-effects.
статья, добавлен 05.03.2013History of the nucleophilic substitution of hydrogen in aromatic compounds, obtaining picric acid. Survey of SNH Substitution. Heterocyclizations Based on SNH Reactions. Intramolecular One-Step SNH Cyclizations; cascade Sequences Based on SNH Reactions.
научная работа, добавлен 05.03.2013Testing scheme of the synthesis of ester atsalamov acids and subsequent cyclization of the intermediate 3-hydrazinopyridazine-2-ones with carbonyl-containing compounds to provide chemical diversity of the final products containing a practical substitute.
статья, добавлен 20.03.2016The study of the synthesis and physicochemical properties of derivatives of 4-phenyl-5-(1,2,3-benzotriazolyl 1)-3-merkapto-1,2,4-triazole(4H). Due to computer prognosis data the substances synthesized are prospective anticonvulsants and antiasthmatics.
статья, добавлен 05.03.2014By Reaction with Alkyl Halides. Nucleophilic Addition. Oxidation of Ring Carbon Atoms Followed by Addition. Reduction of Exocyclic Double Bonds. Ring Cleavage Reactions. Coupling of Pyrazol-3-ones with Aryl Diazonium Salts. Oxidative Coupling, silylation.
учебное пособие, добавлен 05.03.2013Applications heterocyclic compounds; approaches to synthesis. Familiarization with effective conversion of organic compounds into valuable fluorinated products. The use of fluorinated triazoles for the protection of metals and alloys from corrosion.
научная работа, добавлен 05.03.2013Using phosphoric acid and phosphor pent oxide as new catalyst for preparing of derivatives of benzoxazole. Use of benzoaxol ring in medicinal chemistry. Synthesis of 1,3-(Benzene-1,3-diyl) bis(benzoxazole). Synthesis of 3-(2-Hydroxynaphthol) benzoxazole.
статья, добавлен 21.01.2021Benzisothiazolium Salts. Heterocyclic Annulated Isothiazolium Salts. Structure. X-ray Diffraction. Molecular Spectra. Analytical methods. Reactivity, general survey. Oxidation to Sultims and Sultams. Ring Transformation in Other Heterocyclic Compounds.
статья, добавлен 05.03.2013Advances in heterocyclic chemistry. Molecular cascade and the formation of heterocyclic compounds and their impact on cost and waste reduction in the use of natural resources for production, the impact on the environment, energy and resource conservation.
научная работа, добавлен 05.03.2013Carboxymethyl cellulose as the one of largest and most widely used ether. Creating a uniform distribution of reagents in the area of chemical reactions - the process which underlying the modeling of macrokinetics carboxymethylation of cellulose.
статья, добавлен 05.12.2018The transformation of 4-oxo-3,4-dihydroquinazolinone derivatives containing an ester group under the conditions of the Grignard reaction. Investigated acetic acid esters proceeds involving the ester group and the excess. The studying reaction of reagent.
статья, добавлен 01.03.2014Models of 5,10-methylenetetrahydrofolate in organic synthesis and their reactions. Syntheses using mononucleophiles and binucleophiles. Molecular mechanism of carbon transfer reactions. Designs of models of coenzyme 5,10-methylenetetrahydrofolate.
статья, добавлен 05.03.2013The way to save part of the energy released when hydrogen bonds are formed in the form of the energy intensity of their mesh. Conditions for the onset of synchronous transitions of protons from single molecules to molecules of the H-bond network.
статья, добавлен 10.05.2018The structural, theoretical and synthetic properties of enamines which act as important intermediates in many syntheses of organic compounds containing oxygen. Cycloaddition reactions, electrochemistry, hydrolysis and biochemistry of metalated enamines.
книга, добавлен 05.03.2013Convenient method of synthesis of optically active oxamoylaminoacids. Compounds have significant hepatoprotective, antiinflammatory and immunodepressant activities with low toxicity. Influence of investigated sudstances on rarametrs of specific immunity.
статья, добавлен 15.02.2014- 21. A synthetic approach of d-glucose derivatives: spectral characterization and antimicrobial studies
Synthesis of new series of derivatives of methyl 4, 6-o-(4-methoxybenzylidene)-b-D-glucopyranoside direct acylation with a wide range of acylating agents. Spectral and elemental analysis data of antibacterial action of the synthesized compounds.
статья, добавлен 23.02.2016 Some aspects of sugar-derived heterocycles and their precursors which are utilized as the inhibitors against glycogen phosphorylases and are responsible for the release of mono-glucose from poly-glucose. The quantitative structure-activity relationship.
научная работа, добавлен 05.03.20133-Bromo and 3-chloro-3-trifluoroacetyl-1-methyl-2-pyrrolidinones by the halogenation reaction of the corresponding 3-trifluoroacetyl derivatives. Characteristic hydrates after simple filtration on silica gel. The formation of new spirocyclic lactams.
статья, добавлен 14.02.2014Organometallic complexes of Non-Transition Metals with Scandium, Titanium, and Vanadium Group Metals, with Chromium Group Metals, with Three, Two and One Carbonyl Groups. Meaning of polypyridine ligands, especially the formation rhenium and ruthenium.
научная работа, добавлен 05.03.2013Influence of synthesis conditions on ceria particles size. Anticorrosion properties of modified carbon nanotubes. Realization the synthesis in aqueous solution at room temperature that reduces the cost of the preparation procedure of nanosized ceria.
статья, добавлен 04.04.2014