The organometallic chemistry of the transition metals
General properties of organometallic complexes. Metal alkyls and hydrides. Nucleophilic and electrophilic addition. Physical methods in organometallic chemistry. Insertion and Elimination. Homogeneous catalysis. Applications to organic synthesis.
Подобные документы
Catalytic, electrical, optical and magnetic properties of cobalt sulfide. Chemical structure and application of inorganic compounds and salts the sulfurous acid. Brief description of the structure of pyrite. Methods for the synthesis of the metals.
статья, добавлен 30.07.2016Homogeneous precipitation synthesis of nanocomposites - activated carbon – zirconium(IV) oxide. Characterization of samples by x-ray diffraction analysis and electron microscopy. Sorption properties and the degree of extraction of phosphate ions.
статья, добавлен 23.02.2016Modern and effective methods of hardening metals. Nitriding in a glow discharge in ammonia or in an anhydrous medium. Tribological and physicochemical properties of hardened surfaces obtained by nitriding with autonomous and interconnected BATR modes.
статья, добавлен 22.05.2022Properties, combustion, electron energy levels. Elemental molecular forms. Covalent, organic compounds. Hydrides, protons, acids, isotopes. Discovery and use. Role in quantum theory. Natural occurrence, production: laboratory, industrial, thermochemical.
реферат, добавлен 13.11.2009Hydrogenation of these oxygen-stabilized n-phases with Ti2Ni-type structure proceeds through expansion of their unit cells by 15.5 and 17.3%, respectively, without change of the type of metal matrix. Insertion of deuterium atoms into the metal matrix.
статья, добавлен 23.02.2017Thiophene ring closure in pyridine derivatives. Syntheses of tri- and polycyclic systems based on thienopyridines. Pyridine ring closure in thiophene derivatives. Methods for the preparation of thieno[3,2-b]pyridine derivatives and their properties.
статья, добавлен 05.03.2013The study of the synthesis and physicochemical properties of derivatives of 4-phenyl-5-(1,2,3-benzotriazolyl 1)-3-merkapto-1,2,4-triazole(4H). Due to computer prognosis data the substances synthesized are prospective anticonvulsants and antiasthmatics.
статья, добавлен 05.03.2014Consideration of the results of x-ray diffraction of the considered chemical compounds. Structural properties of the films of magnesium oxide. Substantiation of optimum parameters of temperature of synthesis of organic and many inorganic compounds.
статья, добавлен 30.07.2016Study of ternary intermetallic compounds RxMyXz (R = rareearth Element, M = d-metal, X = p-metal). Results of identification of the new R-Au-Al compound. The starting materials for the synthesis of R-Au-Ga. Function of the profile form of pseudo-Voigt.
статья, добавлен 23.02.2017New facile method for the controllable synthesis of high quality single-phase nanowires with from nanowires templates. Detailed characterization of the superconducting and transport properties of nanowires. Synthesis of porous nanowires and nanotubes.
статья, добавлен 30.07.2016The study of the effect of structural relaxation on the basal-plane conductivity of heavily high-Tc single crystals. Increased oxygen deficiency, increased localization effect. The transition metal–insulator transition point toward higher temperatures.
статья, добавлен 02.12.2016Models of 5,10-methylenetetrahydrofolate in organic synthesis and their reactions. Syntheses using mononucleophiles and binucleophiles. Molecular mechanism of carbon transfer reactions. Designs of models of coenzyme 5,10-methylenetetrahydrofolate.
статья, добавлен 05.03.2013Classification of terpenes. Diterpenes - organic compounds of terpenes group consisting of 4 isoprene units. Properties. Application. Drugs of the triterpene saponins. Gliderinin. Bioslastilin. Physical and chemical properties of triterpene saponins.
презентация, добавлен 15.01.2017Magnesium as a chemical element and a silvery-white, light-weight metal. Notable characteristics, applications. As the metal. Incendiary use, in magnesium compounds. History, sources, ores, sea water, electrolysis. Biological role, isotopes, precautions.
реферат, добавлен 13.11.2009The one-step procedure of simultaneous preparation of polyacrylonitrile-based carbon support and Fe-Pd bimetallic nanoparticles. The effect of synthesis conditions on the metal-carbon nanocomposite structural characteristics. The crystallite size.
статья, добавлен 27.08.2020By Reaction with Alkyl Halides. Nucleophilic Addition. Oxidation of Ring Carbon Atoms Followed by Addition. Reduction of Exocyclic Double Bonds. Ring Cleavage Reactions. Coupling of Pyrazol-3-ones with Aryl Diazonium Salts. Oxidative Coupling, silylation.
учебное пособие, добавлен 05.03.2013Physical and chemical properties of the drugs. Reactions to chloride ions Cl- in a solution of AgNO3 in HNO3. Photocolorimetry with painted ferum hydroxamate. Reaction on heterocyclic atom of nitrogen. Using of methods of quantitative determination.
презентация, добавлен 24.11.2016Polymers, inorganic and organic, amorphous and crystalline substances consisting of "Monomeric units" connected in a long macromolecule chemical bonds. Molecular modeling of melting process of solid polymers in the transition and plastic deformation.
статья, добавлен 23.02.2016Experimental study of interaction of water with the substrate and the role of cesium as a promoter for the adsorption of water on the strontium titanate surface. Enhancement of the catalytic properties of metal oxides by the addition of alkali species.
статья, добавлен 30.07.2016Preparing of mesoporous organic-inorganic hybrid composites on glass substrates by the sol-gel method for testing the proteins adhesion. The coatings of colloidal silica, polysiloxane sol methyl-modified sols and with various wettability properties.
статья, добавлен 02.04.2014The method of synthesis of fluorinated heterocycles. The use of mono- and 1,3-dicarbonyl substrates and their nitrogen-containing analogues. Biological activity, physical and chemical properties of heterocyclic compounds with perfluoroalkyl groups.
научная работа, добавлен 05.03.2013Ag-Ni alloy films were electrodeposited from an ammonia solution on copper substrates at various material ratios and current densities. Investigation of electrical conductivity and pH, formation of complexes with silver and nickel. X-ray diffraction.
статья, добавлен 16.01.2021Determine the optimal parameters of synthesis and base properties of nano-tubular crystals Mg-Ni chrysotiles. temperature ranges and pressure for the synthesis of nano-tubular crystals all synthesed chrysotile at the time of isothermal exposure.
статья, добавлен 30.07.2016Influence of synthesis conditions on ceria particles size. Anticorrosion properties of modified carbon nanotubes. Realization the synthesis in aqueous solution at room temperature that reduces the cost of the preparation procedure of nanosized ceria.
статья, добавлен 04.04.2014Chemical properties of organic compounds derived from ammonia. The mechanism of substitution of hydrogen for hydrocarbon radicals within molecules. Classification of the most common amines. Familiarization with the formula for the secondary amine.
презентация, добавлен 06.12.2016