Catalysis of diels-alder reactions in water
Mechanistic aspects of the Diels-Alder reaction. The effect of micelles on it. The effects of Lewis acids on the endo-exo selectivity in water compared to the effects in organic solvents. Enantioselective cid catalysis of an organic reaction in water.
Подобные документы
Physical and chemical properties of the drugs. Reactions to chloride ions Cl- in a solution of AgNO3 in HNO3. Photocolorimetry with painted ferum hydroxamate. Reaction on heterocyclic atom of nitrogen. Using of methods of quantitative determination.
презентация, добавлен 24.11.2016Dextran methacrylates were received by acylation of dextran with methacryloilchloride in the presence of tertiary amines in the DMF/LiCl solution. Dextran methacrylates, obtained in the presence of triethylamine, with DS over 0.5 were insoluble in water.
статья, добавлен 30.08.2016- 28. Kinetics of liquid-phase hydrogenation of n-valeraldehyde to n-amyl alcohol over a Ru/Al2O3 catalyst
Schematic diagram of the experimental setup for hydrogenation. Effect of catalyst loading on initial rates of reaction. The use of gas chromatography for the analysis of the reaction. Langmuir–Hinshelwood-type models for single, dualsite mechanisms.
статья, добавлен 20.10.2014 The transformation of 4-oxo-3,4-dihydroquinazolinone derivatives containing an ester group under the conditions of the Grignard reaction. Investigated acetic acid esters proceeds involving the ester group and the excess. The studying reaction of reagent.
статья, добавлен 01.03.2014Study the process of liquid hydrocarbon oxidation. Chemical reaction of cyclohexane with the organic additives of different nature. Composition of products and speed of oxidation of toluene and p-xylene in the presence of binary liquid catalysts.
статья, добавлен 23.02.2016Characteristics of the initial C9 fraction. Unsaturated hydrocarbons conversion, their concentration. Products of pyrolysis diesel fuel production of ethylene. Cooligomerization of C9 fraction unsaturated hydrocarbons initiated by organic peroxides.
статья, добавлен 23.02.2016Investigation of the influence of electronic effects of substitution of maleic anhydride with hydrazine in acetic acid. Determination of CO stretching vibrations in the middle of the strip plane strain. Characteristics of magnetic shifts quinazolines.
статья, добавлен 17.02.2014Chemical properties of organic compounds derived from ammonia. The mechanism of substitution of hydrogen for hydrocarbon radicals within molecules. Classification of the most common amines. Familiarization with the formula for the secondary amine.
презентация, добавлен 06.12.2016- 34. Study of processes during electrolysis of organic dye solution by means of ion-photon spectrometry
Spectral composition and quantum yield of radiation of the excited particles sputtered by an ion beam from surfaces of the dried sediment formed on electrodes at the electrolysis of the organic dye were studied by the method of ion-photon spectrometry.
статья, добавлен 27.07.2016 Study matter and change and the types of systems. Studying the molecules of life by organic chemistry. Identification and quantification of materials in a mixture in analytical chemistry. Chemical principles underlying basic biological systems.
эссе, добавлен 22.11.2015Brief biographical information about the life of F. Haber - a German chemist and Nobel laureate. Investigation the reaction of nitrogen with hydrogen, which produces ammonia. The essence of Le Chatelier's Principle. The main function of the catalyst.
реферат, добавлен 04.02.2015The efficient synthetic protocol for aminomethylation proceeding was developed which led to obtaining a series of novel 3-(phenylamino)-methyl derivatives of 5,7-dimethyl-6-phenylazo-3Н-thiazolopyridin-2-one. The conditions for aminomethylation reaction.
статья, добавлен 30.08.2016- 38. The experimental study of the effect of raleukin on development of dithizone diabetes in rabbits
Diabetes mellitus in the structure of endocrine diseases. The study of the effect of antioxidant properties of a biological product is a recombinant receptor antagonist Il-1 relacin and hypoglycemic action for major reaction non-enzymatic glycosylation.
статья, добавлен 29.01.2016 Properties, combustion, electron energy levels. Elemental molecular forms. Covalent, organic compounds. Hydrides, protons, acids, isotopes. Discovery and use. Role in quantum theory. Natural occurrence, production: laboratory, industrial, thermochemical.
реферат, добавлен 13.11.2009Critical reviews on "Heterocyclic Compounds" within topic-related volumes dealing with all aspects such as synthesis, reaction mechanisms, structure complexity, reactivity, stability, biology, pharmacological aspects, applications in material sciences.
учебное пособие, добавлен 05.03.2013Carbon as the element essential to all of life, and hence the basis for a vast field of study. Electronegativity value of fluorine. Plastic polystyrene - important product of the hydrocarbon family. Chemical properties of carboxylic acids and esters.
доклад, добавлен 15.09.2014Synthesis of a polymer by the reaction between maleic acid and 2-methylquinoxaline 1,4-dioxide. Using photocatalysis during synthesis. The reaction of the polymer with maleic acid molecules. Determination of the reaction mechanism and polymer structure.
статья, добавлен 03.11.2020Hydrogen evolution reaction (HER) is the cathodic hydrogen evolution reaction in electrolytic cell, but the hydrogen evolution catalytic properties of electrode materials best remains is the precious metal catalyst, has become the research hot spot.
статья, добавлен 10.10.2024Kinetic regularities of epoxy resins modification by aliphatic and aromatic dibasic acids have been studied. The effective rate constants and activation energies of the reactions between epoxy resin and acids by different nature have been calculated.
статья, добавлен 30.08.2016Study the interaction of an order of amino-anthraquinones with benzoylisothiocyanate. The process of obtaining the formation of new N-benzoyl-N '- (9,10-dioxo-9,10-dihydroanthacen-1- yl) -thioureas. Quantumchemical analysis of the passing reaction.
статья, добавлен 23.02.2016Crystals of the [Cu(C4H7N3S)Cl] (1)-complex were synthesized by solvothermal reaction of 2-amino-5-ethyl-1,3,4-thiadiazole (C4H7N3S) with CuCl in hydrochloric acid solution, and studied by X-ray diffraction. 3D hydrogen-bonded framework in complex.
статья, добавлен 23.02.2017Monomers conversion dependence on reaction mixture composition. Consideration of the dependence cooligomer of and its characteristics, average molecular weight. Study of liquid products of pyrolysis of hydrocarbons: styrene and dicyclopentadiene.
статья, добавлен 23.02.2016On the basis of experimental studies and mathematical modeling, the choice of optimal conditions for 2,3-dimethylbuta-1,3-diene and 2-hydroxyethyl methacrylate cyclization reaction with obtaining of 2-hydroxyethyl-1,3,4-trimethylcyclohex-3-carboxylates.
статья, добавлен 23.02.2016The study of physico-chemical properties of modified forms of natural biopolymers – carboxymethyl cellulose and xanthan gums, their ability to film formation water-soluble polymeric compositions and the influence on growth and productivity of crops.
статья, добавлен 23.02.2016Determined of the dissociation (deprotonation) constants of flavones in water-methanol mixtures. Research of features hydroxyflavones, which have been the convenient models for exploration of the intramolecular proton transfer in the excited state.
статья, добавлен 29.09.2016