Spectral and basic properties of flavones in the ground and excited states
Determined of the dissociation (deprotonation) constants of flavones in water-methanol mixtures. Research of features hydroxyflavones, which have been the convenient models for exploration of the intramolecular proton transfer in the excited state.
Подобные документы
- 1. Study of processes during electrolysis of organic dye solution by means of ion-photon spectrometry
Spectral composition and quantum yield of radiation of the excited particles sputtered by an ion beam from surfaces of the dried sediment formed on electrodes at the electrolysis of the organic dye were studied by the method of ion-photon spectrometry.
статья, добавлен 27.07.2016 - 2. Algorithm of optimal solution search for the control with model system of methanol synthesis column
The mechanism of development and implementation of the optimal synthesis search algorithm and analysis of gas costs. Features of control using the maintenance schedule. Technological process of methanol synthesis under conditions close to optimal.
статья, добавлен 14.01.2017 Study of the process of intramolecular cyclization products of epichlorohydrin aminolysis of secondary amines. Analysis of the energy characteristics obtained in vacuum and in acetonitrile solution with water as an "active" solvation partner of reaction.
статья, добавлен 30.10.2016Experimental study of interaction of water with the substrate and the role of cesium as a promoter for the adsorption of water on the strontium titanate surface. Enhancement of the catalytic properties of metal oxides by the addition of alkali species.
статья, добавлен 30.07.2016The efficiency of using softened water in the removal of dissolved oxygen and iron ions has been determined. The dependence of the efficiency in the processes of the deoxygenation and iron removal of water on the filtering speed through the redox filter.
статья, добавлен 26.02.2021The importance of water quality. Applications of machine learning in water quality prediction. Challenges and limitations. Given these multifaceted impacts, the necessity for accurate and timely prediction of water quality cannot be overstated.
статья, добавлен 19.03.2024An ion-pair model has been proposed explaining the origin of acidic sites at the silica surface–aqueous solution interface. Importance of role of the dissociated water is shown in the hydrolysis of the saccharose adsorbed on the surface of silica.
автореферат, добавлен 02.04.2014The chemical structure of the polymer latexes. The influence of surfactants on the drip solution. The mechanism of anionic with a negative charge in the screed, acting as air entrainment. Hydrogen bonding, water absorption and compressive strength.
статья, добавлен 22.02.2015Models of 5,10-methylenetetrahydrofolate in organic synthesis and their reactions. Syntheses using mononucleophiles and binucleophiles. Molecular mechanism of carbon transfer reactions. Designs of models of coenzyme 5,10-methylenetetrahydrofolate.
статья, добавлен 05.03.2013- 10. Review of graphene properties in view of its use as a substrate for matrix-free mass spectrometry
The graphene basic properties is given. The possible role of intrinsic and deliberately induced structural defects in electronic and chemical properties of graphene substrates. Optimized geometric structures for the Stone-Wales defect functionalized.
статья, добавлен 02.04.2014 - 11. A synthetic approach of d-glucose derivatives: spectral characterization and antimicrobial studies
Synthesis of new series of derivatives of methyl 4, 6-o-(4-methoxybenzylidene)-b-D-glucopyranoside direct acylation with a wide range of acylating agents. Spectral and elemental analysis data of antibacterial action of the synthesized compounds.
статья, добавлен 23.02.2016 Development of a thermal model describing the beam-metal, the features of the hyperbolic relaxation of the equation of heat transfer. Characterization of failure mechanisms for irradiated and non-irradiated sample, the changes in their structure and chemi
статья, добавлен 30.07.2016Investigation of the influence intercalation ions of Ni2+ on the electrical properties of indium selenide crystals. The surface of InSe layered crystals. Investigation of magnetic properties of intercalated NiXInSe. The basic samples of InSe.
статья, добавлен 30.07.2016The way to save part of the energy released when hydrogen bonds are formed in the form of the energy intensity of their mesh. Conditions for the onset of synchronous transitions of protons from single molecules to molecules of the H-bond network.
статья, добавлен 10.05.2018Study of the reaction of polyelectrolytes. Research of the structure and membrane properties of sodium carboxymethylcellulose and urea-formaldehyde oligomer. Development of technology for manufacturing biocompatible polymeric materials for medicine.
статья, добавлен 17.02.2019The aim of this study was to determine the quantitative and qualitative determination of fatty acids in the fruits of the plant Zosima absinthifolia, which is widespread in Absheron, as well as to study its physicochemical and organoleptic properties.
статья, добавлен 20.09.2024Mechanistic aspects of the Diels-Alder reaction. The effect of micelles on it. The effects of Lewis acids on the endo-exo selectivity in water compared to the effects in organic solvents. Enantioselective cid catalysis of an organic reaction in water.
книга, добавлен 05.03.2013Crystalline and electronic structures of nanoalumina alone and in different mixtures with nanosilica. X-ray diffraction and ultrasoft X-ray emission spectroscopy. Pore size distributions calculated. Resalts of the OKa emission bands of alumina in samples.
статья, добавлен 20.03.2016Physical parameter models. Thermodynamic parameter models. Brief review of the relationship between the solution model and phase equilibria. The modified quasi chemical (MQC) model. Basic quasi chemical theory. The modified binary quasi-chemical theory.
статья, добавлен 10.04.2017The study of physico-chemical properties of modified forms of natural biopolymers – carboxymethyl cellulose and xanthan gums, their ability to film formation water-soluble polymeric compositions and the influence on growth and productivity of crops.
статья, добавлен 23.02.2016The study of the diffusion of salt water in the soil of Lapidusoia and Verigin. Calculation of leaching rates. Initial and boundary conditions for salt distribution. Analysis of the influence of gravity, pressure and soil resistance on water filtration.
статья, добавлен 19.05.2018Radical polymerization with a thiol-type chain transfer agent of poly-N-vinylpyrrolidone-based amphiphilic polymers, which can be used as drug carriers. Critical micelle concentration and its dependence on the molecular weight of the diblock copolymers.
статья, добавлен 18.04.2022Study of the disinfecting effect of the physical and chemical properties accompanying hydrodynamic cavitation on the sanitary index of microorganisms in water. Model for determining the result of disinfection in conditions of hydrodynamic cavitation.
статья, добавлен 21.12.2016Analysis of spectral characteristics of a steady state (excitation and emission) spectra of photoluminescence of europium included in the single crystal and glassy lithium tetraborate and silica to distinguish oxidation, the site-symmetry and morphology.
статья, добавлен 02.04.2014Influence of the basic nature of finely dispersed microfillers on the kinetics of hydrate release and localization and the degree of its crystallization. Formation of contacts between particles of systems, including various modifications of gypsum.
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