Photoluminescence study of Eu-species incorporated in lithium tetraborate and silica
Analysis of spectral characteristics of a steady state (excitation and emission) spectra of photoluminescence of europium included in the single crystal and glassy lithium tetraborate and silica to distinguish oxidation, the site-symmetry and morphology.
Подобные документы
The study of the effect of structural relaxation on the basal-plane conductivity of heavily high-Tc single crystals. Increased oxygen deficiency, increased localization effect. The transition metal–insulator transition point toward higher temperatures.
статья, добавлен 02.12.2016Study of influence of amino acids on the hydroxyapatite formation. Study of mineral obtained by transmission electron microscopy and powder X-ray diffraction. Analysis of the phase composition, crystal size and lattice microstrains of calcium phosphate.
статья, добавлен 23.12.2016The occurrence of compensation effect on massive and supported oxide catalysts of CO oxidation is shown. The explanation of compensation effect is offered based on the data on the surface state of the catalysts that are obtained means desorption method.
автореферат, добавлен 02.04.2014The crystal structure of racemate R,S-7-bromo-3-ethoxy-5-phenyl-3H-1,4-benzodiazepine- has been compared to the structure of R-enantiomer. It has been determined that crystals of R-enantiomer and R,S-racemate are formed by the similar H-bonded chains.
статья, добавлен 01.03.2014Crystalline and electronic structures of nanoalumina alone and in different mixtures with nanosilica. X-ray diffraction and ultrasoft X-ray emission spectroscopy. Pore size distributions calculated. Resalts of the OKa emission bands of alumina in samples.
статья, добавлен 20.03.2016Study of the electrochemical oxidation of methyl tert-butyl ether on micromodified and composite lead dioxide anodes. Anodic conversion of MTBE and electrochemical processes of water oxidation with formation of hydroxyl radicals and molecular oxygen.
статья, добавлен 30.10.2016A controlling the morphology of zinc hydroxide and zinc oxide at room temperature without using any template or surface ligand. Identify the precipitated materials. Dependence of ZnO morphology on Zn2+ concentration. Scanning electron microscopy of zinc.
статья, добавлен 30.07.2016The X-ray diffraction study of the isotypic structures of I and II reveals that the crystal structure consists of three structural units. The coordination polyhedron of the lanthanide atom. Atomic coordinates and equivalent displacement parameters.
статья, добавлен 23.02.2017Investigation of optical absorption spectra of YAG: Cr, Mg, and GGG: Cr, Mg films during high-temperature annealing in oxidation and reduction atmospheres. Factors to increase in absorption in the visible region, the charge exchange of chromium ions.
статья, добавлен 29.09.2016- 35. Synthesis and crystal structure of an Ag(I) complex of composition (C9H7N(C3H5))2[AgBr2]Br(H2O)2
Coordination behavior of Ag (I) with cations of N-allyl quinolinium. Synthesis of N-allyl quinolinium bromide. Determination of the structure of the x-ray crystal. Bromine ions of the second crystallographic type. Study silver nitrate compounds.
статья, добавлен 23.02.2017 3-Bromo and 3-chloro-3-trifluoroacetyl-1-methyl-2-pyrrolidinones by the halogenation reaction of the corresponding 3-trifluoroacetyl derivatives. Characteristic hydrates after simple filtration on silica gel. The formation of new spirocyclic lactams.
статья, добавлен 14.02.2014Benzisothiazolium Salts. Heterocyclic Annulated Isothiazolium Salts. Structure. X-ray Diffraction. Molecular Spectra. Analytical methods. Reactivity, general survey. Oxidation to Sultims and Sultams. Ring Transformation in Other Heterocyclic Compounds.
статья, добавлен 05.03.2013Historical Developments; the Revival of Troger’s Bases, the Synthesis and Mechanism of Formation. Multiple TB Systems, reactivity. Physicochemical properties, molecular and Crystal Structure; Nuclear Magnetic Resonance Spectra; uses and applications.
научная работа, добавлен 05.03.2013Synthesis semizwitterionic viologens for the crystal engineering of functional materials. Application of the control positions of molecules in crystals using hydrogen bonds. The triple helices had obtained by tunig the spacer between donor and acceptor.
статья, добавлен 17.02.2014Point defects in doped crystals PbTe:Sb and solid solutions. The dependence of the concentration of dominant point defects, charge carriers from the amount of alloying compounds and the magnitude of the initial deviation from stoichiometry in the matrix.
статья, добавлен 24.02.2016The study of the processes of reparative activity diacamph part of the medications suppositories for the treatment of degenerative and inflammatory diseases of the rectum, determination of their crystallographic and thermogravimetric characteristics.
статья, добавлен 29.10.2016The development of selective oxidation of simply accessible dihydroxy-dypropoxycalix[4]arene to nitrocalixmonoquinone by mixture of 75 % nitric acid and glacial acetic acid. Synthone for design of optical sensors and redox-sensitive bio-active compounds.
статья, добавлен 11.02.2014Synthesis of two rare-earth nickel silicide PrNi9Si4 and NdNi9Si4. Their crystal structures, refined from X-ray powder diffraction data, structure type. The two compounds as Curie-Weiss paramagnets due to magnetic moments carried on the rare-earth atoms.
статья, добавлен 23.02.2017Treating the properties of oxidized activated carbon KAU by different temperatures in inert atmosphere were studied by means of DTA, Boehm titration, XPS and AFM methods and their catalytic activity in hydrogen sulphide oxidation was established.
статья, добавлен 04.04.2014A sample of Mg10Ir19B16, prepared from the elements by high-temperature treatment in sealed Ta containers. The chemical composition, confirmed by WDXS analysis. Electronic structure calculations and chemical bonding analysis by the ELI/ED approach.
статья, добавлен 23.02.2017Determined of the dissociation (deprotonation) constants of flavones in water-methanol mixtures. Research of features hydroxyflavones, which have been the convenient models for exploration of the intramolecular proton transfer in the excited state.
статья, добавлен 29.09.2016Dependence of durability of coverages on nature and closeness of adhesive bonds. Use of silanes with an olefine carbon as an adhesion layer on metallic grounds, improves protective properties of coverages a steady-state by an ultraviolet irradiation.
автореферат, добавлен 02.04.2014By Reaction with Alkyl Halides. Nucleophilic Addition. Oxidation of Ring Carbon Atoms Followed by Addition. Reduction of Exocyclic Double Bonds. Ring Cleavage Reactions. Coupling of Pyrazol-3-ones with Aryl Diazonium Salts. Oxidative Coupling, silylation.
учебное пособие, добавлен 05.03.2013Study of the process of intramolecular cyclization products of epichlorohydrin aminolysis of secondary amines. Analysis of the energy characteristics obtained in vacuum and in acetonitrile solution with water as an "active" solvation partner of reaction.
статья, добавлен 30.10.2016- 50. Study of processes during electrolysis of organic dye solution by means of ion-photon spectrometry
Spectral composition and quantum yield of radiation of the excited particles sputtered by an ion beam from surfaces of the dried sediment formed on electrodes at the electrolysis of the organic dye were studied by the method of ion-photon spectrometry.
статья, добавлен 27.07.2016