The quantum-chemical investigation of n-cyclization reaction mechanism for epichlorohydrin aminolysis products
Study of the process of intramolecular cyclization products of epichlorohydrin aminolysis of secondary amines. Analysis of the energy characteristics obtained in vacuum and in acetonitrile solution with water as an "active" solvation partner of reaction.
Подобные документы
The using nickel powders as electrode materials in multilayered ceramic capacitors. Development of technology of Ni/NiO nanopowders obtaining with particle size of 20 nm and minimal impurities content. The analyses of powder microstructure the products.
статья, добавлен 30.07.2016A new amine-functionalized graphene oxide nanosheet was prepared via covalently grafting reaction. Results showed that adsorption capacity of GO was significantly improved by amine functionalization. The Langmuir isotherm and pseudosecond kinetic model.
статья, добавлен 15.01.2021Physical parameter models. Thermodynamic parameter models. Brief review of the relationship between the solution model and phase equilibria. The modified quasi chemical (MQC) model. Basic quasi chemical theory. The modified binary quasi-chemical theory.
статья, добавлен 10.04.2017- 54. Algorithm of optimal solution search for the control with model system of methanol synthesis column
The mechanism of development and implementation of the optimal synthesis search algorithm and analysis of gas costs. Features of control using the maintenance schedule. Technological process of methanol synthesis under conditions close to optimal.
статья, добавлен 14.01.2017 Combination of methods quantum chemistry. Geometrical and electronic structure of clinoptilolite clusters modified by zinc and calcium. Redistribution of electronic density on the oxygen atoms of clusters during formation of bonds with zinc and calcium.
статья, добавлен 23.02.2016The development of rape-cake extract as eco-friendly volatile corrosion inhibitors. Analysis of volatiles by GC-MS. Theoretical study of molecular spatial structure, causes of the shortage of the energy and density of the extract, its key compounds.
статья, добавлен 23.02.2016Experimental study of interaction of water with the substrate and the role of cesium as a promoter for the adsorption of water on the strontium titanate surface. Enhancement of the catalytic properties of metal oxides by the addition of alkali species.
статья, добавлен 30.07.2016Characteristics: chemical properties, compounds, spectroscopy, isotopes. History, commercial production. Applications, biological role: maintaining body fluid volume in animals, maintaining electric potential in animal tissues. Dietary uses, precautions.
реферат, добавлен 13.11.2009Obtaining JBW zeolite from hydrogels under hydrothermal conditions by alkaline reaction using NaOH as an activating agent. Orthorhombic space group Pmc21 with unit cell parameters, X-ray powder diffraction. Comprehensive study of the synthetic zeotype.
статья, добавлен 18.01.2021Study of swelling kinetics as compared to solvents of various nature (water in various pH, ethanol, toluene) was carried out. IR comparative spectra were obtained for different composites. High anti-bacterial action of the synthesized nanocomposites.
статья, добавлен 30.07.2016The study of physico-chemical properties of modified forms of natural biopolymers – carboxymethyl cellulose and xanthan gums, their ability to film formation water-soluble polymeric compositions and the influence on growth and productivity of crops.
статья, добавлен 23.02.2016Rubidium as a chemical element and a soft, silvery-white metallic element of the alkali metal group. Characteristics, history, occurrence rubidium. Isotopes, uses and applications. Compounds, rubidium chloride. Precautions and biological effects.
реферат, добавлен 13.11.2009- 63. Study of processes during electrolysis of organic dye solution by means of ion-photon spectrometry
Spectral composition and quantum yield of radiation of the excited particles sputtered by an ion beam from surfaces of the dried sediment formed on electrodes at the electrolysis of the organic dye were studied by the method of ion-photon spectrometry.
статья, добавлен 27.07.2016 Systematic studies on the preparation of sodium silicate solutions of different compositions via the hydrothermal microwave treatment of perlite with an NaOH solution. The effect of various factors on the degree of SiO2 recovery and the reaction rate.
статья, добавлен 07.01.2017- 65. Quantum-dimensional effects in thermoelectric characteristics of lead chalcogenides nanostructures
Thermoelectric parameters of the thickness of the layer of nanostructures in the approximation of the variable of the Fermi energy. The Seebeck coefficient, electrical conductivity and their dependence on the pit width for nanofilms of lead chalcogenides.
статья, добавлен 24.02.2016 Study crystallographic sequence of the phase transition in zirconium dioxide at heated. The transformation of monoclinic phase in tetragonal modification. The appearance of new anion vacancies, which form at evaporation of the oxygen from the lattice.
статья, добавлен 30.07.2016Study of the reaction of polyelectrolytes. Research of the structure and membrane properties of sodium carboxymethylcellulose and urea-formaldehyde oligomer. Development of technology for manufacturing biocompatible polymeric materials for medicine.
статья, добавлен 17.02.2019Established based on the theory of nuclear interactions and data on the binding energy of nucleons for the set of known nuclides. Familiarization with fragment of the periodic table of chemical elements. Characteristic of parameters of the metric tensor.
статья, добавлен 29.04.2017The sequence of structural transformations occurring during the thermolysis of the solid solution of diphosphates of composition Zn-Co(II). The composition, temperature ranges of formation and stability of the products of partial, complete dewatering.
статья, добавлен 23.02.2017Reductive opening of heterocycles as a source of functionalized organolithium compounds. Methods for homologation of heterocycles. Double lithiation of thianthrene. Phthalan: a versatile starting material. Homologation of six-membered heterocycles.
статья, добавлен 05.03.2013Chemical derivatives of 1,2,4-thiazole as biologically active chemicals intended for the protection of plants for agricultural purposes, such as biocides and fungicides when preserving books. Impact of chemicals on humans, animals and the environment.
статья, добавлен 21.07.2018Study of influence of amino acids on the hydroxyapatite formation. Study of mineral obtained by transmission electron microscopy and powder X-ray diffraction. Analysis of the phase composition, crystal size and lattice microstrains of calcium phosphate.
статья, добавлен 23.12.2016The results of treatment of solutions with high sulphates concentration and the high level of water hardness. Reduction of secondary pollution by chlorides through the integrated use of the hydrochloride of aluminum and sodium aluminate coagulants.
статья, добавлен 23.02.2016The role of the technique of volumetric titration with a working solution of sodium thiosulfate with a visual indication of the starch equivalence point during the analysis of the residual active chlorine. Evaluation of its advantages and disadvantages.
статья, добавлен 10.05.2018Determined of the dissociation (deprotonation) constants of flavones in water-methanol mixtures. Research of features hydroxyflavones, which have been the convenient models for exploration of the intramolecular proton transfer in the excited state.
статья, добавлен 29.09.2016